Urban mobility services based on user virtualization and social IoT

Smart cities are characterized by smart heterogeneous devices that can interact and cooperate with each other by exchanging regularly low amounts of data in the context of IoT. Lately, there has been an increasing interest in enhancing the IoT paradigm to support exchange of multimedia data. This paper focuses on the concept of Urban Mobility Services and in particular on proposing a solution to enable best QoS and load balance in a 5G network context. The paper introduces a novel algorithm for MobilIty Services uSer vIrtualizatiON (MISSION). MISSION employs cloud computing and broadcast of multimedia content in order to reduce the network load, the number of interactions, and user device energy consumption. It also relies on rating of network reputation in the 5G heterogeneous network environment and performing network selection in the quest to maximize QoS parameters. The performance of the proposed solution is compared against that of a TraffictYpe-based DifferEntiated Reputation (TYDER) algorithm. This performance was evaluated in terms of QoS parameters such as delay, latency, packet loss and prediction error. The results show how MISSION outperforms TYDER in urban mobility scenario

effective linewidth in raman spectra of titanium dioxide nanocrystals

Raman spectra of nanocrystals titanium dioxide are discussed and the correlation between the band shape of the allowed A1g Raman mode and the crystals dimensions is discussed. Data on Raman spectra are reconsidered in the frame- work of a modified "hard confinement" model (MHC). The proposed model is based on the idea of using an effective linewidth parameter, which is a function of the effective dimension of the nanostructure, in spite of the intrinsic Raman band linewidth. The comparison with standard hard confinement model reveals better agreement with the experimental results for the MHC model up to 6 nm. Moreover, the analysis permits to improve the knowledge of the phonon dispersion curve as well as the intrinsic Raman bulk parameters. An analytical form of the size-dependent peak-position in nanocrystals, useful for an approximated size estimation, has been explicated. The general structure of the model permits to extended the MHC to other nano-sized materials

Photoluminescence characterization of aged and regenerated mesoporous silica

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A Social Internet of Things Smart City Solution for Traffic and Pollution Monitoring in Cagliari

In the last years, the smart city paradigm has been deeply studied to support sustainable mobility and to improve human living conditions. In this context, a new smart city based on Social Internet of Things paradigm is presented in this article. Starting from the tracking of all vehicles (that is, private and public) and pedestrians, integrated with air quality measurements (that is, in real time by mobile and fixed sensors), the system aims to improve the viability of the city, both for pedestrian and vehicular users. A monitoring network based on sensors and devices hosted on board in local public transport allows real time monitoring of the most sensitive areas both from traffic congestion and from an environmental point of view. The proposed solution is equipped with an appropriate intelligence that takes into account instantaneous speed, type of traffic, and instantaneous pollution data, allowing to evaluate the congestion and pollution condition in a specific moment. Moreover, specific tools support the decisions of public administration facilitating the identification of the most appropriate actions for the implementation of effective policies relating to mobility. All collected data are elaborated in real time to improve traffic viability suggesting new directions and information to citizens to better organize how to live in the city

Apparent digestibility of insect protein meals for rainbow trout

Insect meals are considered to be promising future ingredients for aquaculture feeds. In past feeding trials in rainbow trout, insect meals were included in diets only on the basis of their nutrients content and energy density without taking into account their biological availability due to the lack of their digestible values. Apparent digestibility (ADC) provides good indication of the bioavailability of nutrients and energy thus providing rational basis for the correct inclusion of feedstuffs. The aim of this research was to assess, in an in vivo trial on rainbow trout, the ADC of five full fat insect meals: one Tenebrio molitor (TM), two Hermetia illucens obtained through two different process (HI1 and HI2), one Musca domestica (MD), and one Alphitobius diaperinus (AD). Fish were fed a high-quality reference diet (R) and test diets obtained mixing the R diet with each of the test ingredients at a ratio of 70:30. Diets contained 1% celite as inert marker. Fish were fed to visual satiety twice a day and faecal samples collected using a continuous automatic device. Faeces were freeze dried and frozen (-20 \ub0C) until analyses. The ADC of dry matter, crude protein and ether extract of each insect meal diet were calculated. ADC for dry matter varied between 70.07 (HI1) and 80.85 (TM). ADC for protein was above 84% in all treatments and resulted the highest in MD, TM and AD treatments. Ether extract apparent digestibility significantly differed among diets with the highest value reported for TM treatment. All treatments reported values higher than 96%. Observed differences could be due to the insect species and meal treatment but in general, tested insect meals were highly digestible for rainbow trout. The results from this research could be useful to optimize the diet formulation

Optical properties of Ge-oxygen defect center embedded in silica films

The photo-luminescence features of Ge-oxygen defect centers in a 100nm thick Ge-doped silica film on a pure silica substrate were investigated by looking at the emission spectra and time decay detected under synchrotron radiation excitation in the 10-300 K temperature range. This center exhibits two luminescence bands centered at 4.3eV and 3.2eV associated with its de-excitation from singlet (S1) and triplet (T1) states, respectively, that are linked by an intersystem crossing process. The comparison with results obtained from a bulk Ge-doped silica sample evidences that the efficiency of the intersystem crossing rate depends on the properties of the matrix embedding the Ge-oxygen defect centers, being more effective in the film than in the bulk counterpart.Comment: 10 pages, 3 figures, in press on J. Non cryst. solids (2007

Persistent photoconductivity and optical quenching of photocurrent in GaN layers under dual excitation

Persistent photoconductivity (PPC) and optical quenching (OQ) of photoconductivity (PC) were investigated in a variety of n-GaN layers characterized by different carrier concentrations, luminescence characteristics, and strains. The relation between PPC and OQ of PC was studied by exciting the samples with two beams of monochromatic radiation of various wavelengths and intensities. The PPC was found to be excited by the first beam with a threshold at 2.0 eV, while the second beam induces OQ of PC in a wide range of photon energies with a threshold at 1.0 eV. The obtained results are explained on the basis of a model combining two previously put forward schemes with electron traps playing the main role in PPC and hole traps inducing OQ of PC. The possible nature of the defects responsible for optical metastability of GaN is discussed. © 2003 American Institute of Physics.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/69582/2/JAPIAU-94-6-3875-1.pd

Balanced replacement of fish meal with Hermetia illucens meal allows efficient hepatic nutrient metabolism and increases fillet lipid quality in gilthead sea bream (Sparus aurata)

In the present study, gilthead sea bream (Sparus aurata) was reared using sustainable feeds containing insect meal from Hermetia illucens larvae. Proteomics and proton nuclear magnetic resonance-based metabolomics analysis were used to assess the metabolic impact of the tested feeds in sea bream liver, whereas the composition of muscle fillets was characterized by means of metabolomics and gas chromatography of fatty acid methyl esters. Including 10% of insect meal while correspondingly reducing fish meal did not substantially alter the metabolism of dietary nutrients, leading to small but significant effects solely on lauric acid content of sea bream fillets. Furthermore, a few alterations in some markers of immune response, such as leukocyte elastase inhibitor-like, granzyme B (G, H)-like, and two associated ortholog groups, serpin B and chymase, were found. In the fish group fed with insect meal, liver morphology analysis showed no structural damage or inflammation and a lower amount of hepatic lipid deposition and accumulation